76-89-1
- Product Name：Methyl benzilate
- Molecular Formula：C15H14 O3
- Purity：99%
- Molecular Weight：242.274
Product Details
Good factory exports good Methyl benzilate 76-89-1
- Molecular Formula:C15H14 O3
- Molecular Weight:242.274
- Appearance/Colour:white crystalline powder
- Vapor Pressure:0.000134mmHg at 25°C
- Melting Point:73-76 ºC
- Refractive Index:1.579
- Boiling Point:187 ºC (13 mmHg)
- PKA:11.38±0.29(Predicted)
- Flash Point:113.3 °C
- PSA：46.53000
- Density:1.189 g/cm3
- LogP:2.09550
Methyl benzilate(Cas 76-89-1) Usage
InChI:InChI=1/C15H14O3/c1-18-14(16)15(17,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11,17H,1H3
76-89-1 Relevant articles
A Unified Strategy for the Asymmetric Synthesis of Highly Substituted 1,2-Amino Alcohols Leading to Highly Substituted Bisoxazoline Ligands
Shrestha, Bijay,Rose, Brennan T.,Olen, Casey L.,Roth, Aaron,Kwong, Adon C.,Wang, Yang,Denmark, Scott E.
supporting information, p. 3490 - 3534 (2021/02/16)
A general procedure for the asymmetric s...
1,5,7-Triazabicyclo[4.4.0]dec-5-ene Enhances Activity of Peroxide Intermediates in Phosphine-Free α-Hydroxylation of Ketones
Wang, Yongtao,Lu, Rui,Yao, Jia,Li, Haoran
supporting information, p. 6631 - 6638 (2021/02/05)
The critical role of double hydrogen bon...
Time-Economical Synthesis of Diarylacetates Enabled by TfOH-Catalyzed Arylation of α-Aryl-α-Diazoesters with Arenes
Hu, Sha,Wu, Jiale,Lu, Zuolin,Wang, Jiaqi,Tao, Yuan,Jiang, Meifen,Chen, Fener
, p. 2559 - 2563 (2021/04/09)
Diarylacetates are privileged structures...
Room Temperature Coupling of Aryldiazoacetates with Boronic Acids Enhanced by Blue Light Irradiation
da Silva, Amanda F.,Afonso, Marco A. S.,Cormanich, Rodrigo A.,Jurberg, Igor D.
supporting information, p. 5648 - 5653 (2020/04/22)
A visible-light-promoted photochemical p...
76-89-1 Process route
-
-
530-48-3
1,1-Diphenylethylene
-
-
882-59-7
1,1-diphenyloxirane
-
-
76-89-1
methyl benzilate
| Conditions | Yield |
|---|---|
|
With
methyl α-hydroperoxy-α,α-diphenylacetate; oxygen;
In
tetrachloromethane;
at 60 ℃;
for 7h;
|
85% 90% |
-
-
538-74-9
dibenzyl sulfide
-
-
621-08-9
Dibenzyl sulfoxide
-
-
76-89-1
methyl benzilate
| Conditions | Yield |
|---|---|
|
With
methyl α-hydroperoxy-α,α-diphenylacetate;
In
chloroform-d1;
at 25 ℃;
for 24h;
Yield given;
|
93 % Spectr. |
76-89-1 Upstream products
-
67-56-1
methanol
-
76-93-7
Benzilic acid
-
124-41-4
sodium methylate
-
134-81-6
benzil
76-89-1 Downstream products
-
3321-80-0
(+)-3-MPB
-
4746-88-7
2-hydroxy-2,2-diphenyl-N-(2-piperidin-1-yl-ethyl)-acetamide
-
853787-58-3
acetoacetyloxy-diphenyl-acetic acid methyl ester
-
102477-86-1
2-hydroxy-2,2-diphenyl-1-o-tolyl-ethanone
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