124-40-3
- Product Name：Dimethylamine
- Molecular Formula：C2H7N
- Purity：99%
- Molecular Weight：45.0843
Product Details
High quality purity >99% Dimethylamine 124-40-3 for sale
- Molecular Formula:C2H7N
- Molecular Weight:45.0843
- Appearance/Colour:colourless compressed liquefied gas
- Vapor Pressure:3.35E-05mmHg at 25°C
- Melting Point:-93 °C
- Refractive Index:1.347
- Boiling Point:6.1 °C at 760 mmHg
- Flash Point:60°F
- PSA：12.03000
- Density:0.68 g/cm3
- LogP:0.22650
Dimethylamine(Cas 124-40-3) Usage
|
General Description |
Dimethylamine is a secondary amine used as a reagent in various chemical reactions, including the synthesis of indole carboxylates, Mannich reactions, and Eschenmoser-Mannich reactions, where it participates in the formation of intermediates or final products such as amino-substituted furanones and σ-receptor ligands. It is also involved in rearrangement-cleavage reactions of ammonium salts, yielding products like aldehydes. Additionally, dimethylamine derivatives have been explored for their potential pharmacological activity, though some studies report low yields or instability in certain reaction pathways. |
InChI:InChI=1/C2H7N/c1-3-2;1-5(2,3)4/h3H,1-2H3;(H2,1,2,3,4)/p-2
124-40-3 Relevant articles
Combustion and sublimation calorimetric studies on acetylurea and trimethyl isocyanurate
Imamura, Akira,Murata, Shigeo,Sakiyama, Minoru
, p. 389 - 396 (1988)
Standard enthalpies of formation in the ...
Thermal decomposition of trimethylamine borane as a precursor to nanocrystalline CVD BC x N y films
Korobeinichev,Shmakov,Chernov,Kosinova,Sulyaeva,Kuznetsov
, p. 1199 - 1204 (2011)
We have studied the kinetics of BC x N y...
Poly(iminoborane)s: An Elusive Class of Main-Group Polymers?
Ayhan, Ozan,Eckert, Thomas,Plamper, Felix A.,Helten, Holger
, p. 13321 - 13325 (2016)
The significance of inorganic main-group...
Silicoaluminophosphate molecular sieve DNL-6: Synthesis with a novel template, N,N″-dimethylethylenediamine, and its catalytic application
Wu, Pengfei,Yang, Miao,Zhang, Wenna,Zeng, Shu,Gao, Mingbin,Xu, Shutao,Tian, Peng,Liu, Zhongmin
, p. 1511 - 1519 (2018)
DNL-6, a silicoaluminophosphate (SAPO) m...
Selective Synthesis of Trimethylamine by Catalytic N-Methylation of Ammonia and Ammonium Chloride by utilizing Carbon Dioxide and Molecular Hydrogen
Beydoun, Kassem,Thenert, Katharina,Streng, Emilia S.,Brosinski, Sandra,Leitner, Walter,Klankermayer, Jürgen
, p. 135 - 138 (2016)
The synthesis of trimethylamine (TMA) th...
Enhanced catalytic reduction of N-nitrosodimethylamine over bimetallic Pd-Ni catalysts
Chen, Huan,Li, Ting,Jiang, Fang,Wang, Zhe
, p. 167 - 177 (2016)
Catalytic reduction of N-nitrosodimethyl...
The nonenzymatic decomposition of guanidines and amidines
Lewis, Charles A.,Wolfenden, Richard
, p. 130 - 136 (2014)
To establish the rates and mechanisms of...
Investigating the Underappreciated Hydrolytic Instability of 1,8-Diazabicyclo[5.4.0]undec-7-ene and Related Unsaturated Nitrogenous Bases
Hyde, Alan M.,Calabria, Ralph,Arvary, Rebecca,Wang, Xiao,Klapars, Artis
, p. 1860 - 1871 (2019)
The widespread use of amidine and guanid...
Application of the WATR technique for water suppression in 1H NMR spectroscopy in determination of the kinetics of hydrolysis of neostigmine bromide in aqueous solution
Ferdous,Waigh
, p. 559 - 562 (1993)
Both ammonium chloride and guanidinium c...
Efficient intramolecular nucleophilic catalysis in the base-catalyzed hydrolysis of o-(1-hydroxyalkyl)-N,N-dimethylbenzenesulfonamides
Drijfhout,Wagenaar,Engberts
, p. 2423 - 2426 (1986)
-
Standard enthalpies of formation of crystalline dimethylammoniumdimethyldithiocarbamate and of dimethyldithiocarbamate complexes of copper(II) and nickel(II). The mean Cu-S and Ni-S bond-dissociation enthalpies
Silva, Manuel A. V. Ribeiro da,Reis, Ana M. M. V.,Faria, Rita I. M. C. P.
, p. 1365 - 1372 (1995)
The standard (p0 = 0.1 MPa) enthalpies o...
Reactions of Carbonyl Compounds in Basic Solutions. Part 27.1 Alkaline Hydrolysis of Bridged Benz[de]isoquinolin-1-ones: Torsionally Distorted Lactams
Bowden, Keith,Hiscocks, Simon P.
, p. 96 - 97 (1997)
Rate coefficients have been measured for...
One-pot synthesis of isoquinolinium salts by rhodium-catalyzed C-H bond activation: Application to the total synthesis of oxychelerythrine
Jayakumar, Jayachandran,Parthasarathy, Kanniyappan,Cheng, Chien-Hong
, p. 197 - 200 (2012)
It's worth its salt: The title reaction ...
Thiophene site activation: Synthesis and structures of Fischer carbene complexes with 3,3′- and 2,3′-bithienyl substituents
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, p. 193 - 207 (2019)
Deprotonation of the reactive α-thiophen...
Synthesis of Methylamines from Carbon Dioxide and Ammonia
Gredig, Silvia V.,Koeppel, Rene A.,Baiker, Alfons
, p. 73 - 74 (1995)
Methylamines were synthesized from carbo...
A comparative study on the hydrolysis of acetic anhydride and N,N-dimethylformamide: Kinetic isotope effect, transition-state structure, polarity, and solvent effect
Cooper, William C.,Chilukoorie, Abhinay,Polam, Suhesh,Scott, Dane,Wiseman, Floyd
, (2017)
Recent studies have shown that general-b...
Pushing the limits of energetic materials - The synthesis and characterization of dihydroxylammonium 5,5′-bistetrazole-1,1′- diolate
Fischer, Niko,Fischer, Dennis,Klapoetke, Thomas M.,Piercey, Davin G.,Stierstorfer, Joerg
, p. 20418 - 20422 (2012)
The safe preparation and characterizatio...
Scanning electrochemical microscopy: Kinetics of chemical reactions following electron-transfer measured with the substrate-generation-tip-collection mode
Martin, Rachel D.,Unwin, Patrick R.
, p. 753 - 759 (1998)
The substrate-generation-tip-collection ...
UV direct photolysis of N-nitrosodimethylamine (NDMA): Kinetic and product study
Stefan, Mihaela I.,Bolton, James R.
, p. 1416 - 1426 (2002)
The ultraviolet (UV) direct photolysis o...
Determination of 18O Exchange Accompanying Basic Hydrolysis of p-Toluamide and N,N-Dimethyl-p-toluamide
Slebocka-Tilk, H.,Brown, R. S.
, p. 1153 - 1156 (1988)
The base-catalyzed hydrolysis and 18O-ex...
Effect of water during the quantitation of formate in photocatalytic studies on CO2 reduction in dimethylformamide
Paul, Avishek,Connolly, Damian,Schulz, Martin,Pryce, Mary T.,Vos, Johannes G.
, p. 1977 - 1979 (2012)
The effect of the water concentration on...
Aminoborane polymers as precursors of C-N-B ceramic materials
Maya
, p. 1104 - 1107 (1988)
Aminoborane polymers were prepared via c...
Formic acid: A future bridge between the power and chemical industries
Supronowicz,Ignatyev,Lolli,Wolf,Zhao,Mleczko
, p. 2904 - 2911 (2015)
In the future hydrogen economy, formic a...
Acid-catalysed chlorine transfer from N-chloramines to iodide ion: Experimental evidence for a predicted change in mechanism
Calvo, Paula,Crugeiras, Juan,Rios, Ana
, p. 4137 - 4142 (2010)
Rate constants for acid catalysis of the...
REACTIONS OF ALLYLIC COMPOUNDS SUCH AS ALLYL ALCOHOLS, ALLYL ETHERS, AND ALLYLAMINES USING trans-Mo(N2)2(Ph2PCH2CH2PPh2)2
Tatsumi, T.,Hashimoto, K.,Tominaga, H.,Mizuta, Y.,Hata, K.,et al.
, p. 105 - 112 (1983)
Double-bond migration of allylic alcohol...
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Norris,W.P.
, p. 1965 - 1972 (1972)
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The rate of spontaneous decarboxylation of amino acids [1]
Snider,Wolfenden
, p. 11507 - 11508 (2000)
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-
Richarz et al.
, p. 2212 (1959)
-
Shape-selective synthesis of methylamines over the RRO zeolite Al-RUB-41
Tijsebaert, Bart,Yilmaz, Bilge,Mueller, Ulrich,Gies, Hermann,Zhang, Weiping,Bao, Xinhe,Xiao, Feng-Shou,Tatsumi, Takashi,De Vos, Dirk
, p. 246 - 252 (2011)
Aluminum was incorporated into the layer...
Absence of stereoelectronic control in the hydrolysis of fully and partially N-alkylated cyclic amidinium ions
Perrin, Charles L.,Thoburn, John D.
, p. 3140 - 3145 (1993)
Deslongchamps' hypothesis of stereoelect...
Reduction of N-nitrosodimethylamine with granular iron and nickel-enhanced iron. 1. Pathways and kinetics
Odziemkowski,Gui,Gillham
, p. 3489 - 3494 (2000)
Laboratory batch and column tests were c...
An Unusual Suppression of Trimethylamine Formation in the High Temperature Alkylation of Ammonia with Methanol over (NH4)3PW12O40
Nasikin, Mohammad,Nakamura, Ryuichi,Niiyama, Hiroo
, p. 209 - 212 (1993)
A synthesis of methylamines from ammonia...
Proton-Coupled Reduction of an Iron Cyanide Complex to Methane and Ammonia
Rittle, Jonathan,Peters, Jonas C.
, p. 12262 - 12265 (2016)
Nitrogenase enzymes mediate the six-elec...
A new route to α-hetero β-enamino esters using a mild and convenient solvent-free process assisted by focused microwave irradiation
Dahmani, Zohra,Rahmouni, Mustapha,Brugidou, Richard,Bazureau, Jean Pierre,Hamelin, Jack
, p. 8453 - 8456 (1998)
New α-hetero β-enamino esters 5 (X = NH,...
REACTIONS INVOLVING FLUORIDE ION. PART 21 . NUCLEOPHILIC SUBSTITUTION REACTIONS OF PERFLUOROCYCLOBUTENE OLIGOMERS
Chambers, Richard D.,Taylor, Graham
, p. 161 - 182 (1980)
Reaction of perfluorocyclobutene oligome...
Adsorption and photocatalytic degradation of gas-phase UDMH under simulated sunlight by AgBr/TiO2/rGA
Ruomeng, Hou,Ying, Jia,Xiaomeng, Lv,Yuanzheng, Huang,Keke, Shen
, p. 12583 - 12594 (2021)
The degradation of UDMH has long been a ...
Thermal Stability of Three Amines in Pressurized Water-Reactor Secondary Systems. Laboratory and Loop Experiments
Feron, Damien,Lambert, Irma
, p. 919 - 932 (1992)
Laboratory and loop tests have been carr...
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Shaw,Walker
, p. 4329 (1957)
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Scanning Electrochemical Microscopy. 9. Theory and Application of the Feedback Mode to the Measurement of Following Chemical Reaction Rates in Electrode Processes
Unwin, Patrick R.,Bard, Allen J.
, p. 7814 - 7824 (1991)
The use of the scanning electrochemical ...
Synthesis and Characterization of Tungsten Nitrido Amido Guanidinato Complexes as Precursors for Chemical Vapor Deposition of WNxCy Thin Films
Nolan, Michelle M.,Touchton, Alexander J.,Richey, Nathaniel E.,Ghiviriga, Ion,Rocca, James R.,Abboud, Khalil A.,McElwee-White, Lisa
, p. 46 - 53 (2018)
Tungsten nitrido amido guanidinato compl...
Formal synthesis of cortistatins
Fang, Lichao,Chen, Yuan,Huang, Jun,Liu, Lianzhu,Quan, Junmin,Li, Chuang-Chuang,Yang, Zhen
, p. 2479 - 2487 (2011)
A unified strategy toward the asymmetric...
Reactions of Alkylnitrosoureas in Aqueous Solution
Snyder, John K.,Stock, Leon M.
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The acid- and base-catalyzed decompositi...
A Small Covalent Allosteric Inhibitor of Human Cytomegalovirus DNA Polymerase Subunit Interactions
Chen, Han,Coseno, Molly,Ficarro, Scott B.,Mansueto, My Sam,Komazin-Meredith, Gloria,Boissel, Sandrine,Filman, David J.,Marto, Jarrod A.,Hogle, James M.,Coen, Donald M.
, p. 112 - 118 (2017)
Human cytomegalovirus DNA polymerase com...
TiO2-reduced graphene oxide for the removal of gas-phase unsymmetrical dimethylhydrazine
Ruomeng, Hou,Ying, Jia,Yuanzheng, Huang,Keke, Shen,Huixin, Zhu
, p. 394 - 402 (2021)
Unsymmetrical dimethylhydrazine (UDMH) c...
Absolute Rates of Recombination and Disproportination of Dimethylaminyl Radicals
Lazarou, Yannis G.,Papagiannakopoulos, Panos
, p. 9133 - 9140 (1993)
The absolute rate constants for the reco...
Kinetics and mechanism of oxidation of metformin hydrochloride by hexamolybdocobaltate(III) in acidic medium
Sawant,Patil,Gokavi
, p. 15 - 20 (2021/01/06)
The oxidation of metformin hydrochloride...
Degradation of gaseous unsymmetrical dimethylhydrazine by vacuum ultraviolet coupled with MnO2
Huang, Yuanzheng,Jia, Ying,Shen, Keke,Hou, Ruomeng,Zhang, Yongyong,Hou, Li'an
supporting information, p. 1194 - 1202 (2021/02/06)
In this study, α-, β-, and δ-MnO2 were p...
124-40-3 Process route
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103-83-3
N,N'-dimethylbenzylamine
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75-24-1
trimethylaluminum
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100-41-4,27536-89-6
ethylbenzene
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103-29-7
1,1'-(1,2-ethanediyl)bisbenzene
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-
124-40-3
dimethyl amine
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108-88-3,15644-74-3,16713-13-6
toluene
| Conditions | Yield |
|---|---|
|
In
benzene;
for 50h;
Irradiation;
|
53% 20% |
-
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7360-02-3
2,4,6-tris(dimethylamino)borazene
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10043-11-5
boron nitride
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124-40-3
dimethyl amine
| Conditions | Yield |
|---|---|
|
With
ammonia;
In
toluene;
excess ammonia condensed into a toluene soln. of B-compd. at -78°C, stirred for 5 h, warmed to 25°C, reluxed for 5 h (under N2), cooled, filtered, washed with toluene, pyrolized at 900°C, heated at 1200°C for 12 h in Ar;
|
124-40-3 Upstream products
-
123-75-1
pyrrolidine
-
68897-42-7
N′,N″-diisopropyl-N,N-dimethyl guanidine
-
110-89-4
piperidine
-
496-15-1
1-indoline
124-40-3 Downstream products
-
108-01-0
2-(N,N-dimethylamino)ethanol
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1704-62-7
1-O-Dimethylaminoethyl-ethylenglykol
-
108-02-1
captamine
-
108-00-9
N,N-dimethylethylenediamine
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